Yes, I could re-structure it like that, but links I am wanting to be main non expandable items would need to be moved into a category and thus be initially hidden.
I am getting outputs for wfParentRow, and wfInner, here is adjusted snippet code for you to see better:
<!-- ########################### NAV START ########################### -->
<div id="site-nav">
<div id="Nav">
<li class="first active"><a href="http://127.0.0.1/Dev/cms/modx/www_revolution/" title="Home" >Home</a></li>
<!-- wfParentRow start -->
<div class='NavType1Expander' id="nav6"><a href='#'>Curriculum Vitae</a></div>
<div class='NavType1Container' id="nav6Body">
<ul>
<!-- wfInner -->
<!-- wfInnerRowTpl -->
</ul>
</div>
<div class='NavType1ExpanderBase'></div>
<!-- wfParentRow end -->
<li><a href="index.php?id=8" title="Work history" >Work history</a></li>
<li><a href="index.php?id=9" title="Portfolio" >Portfolio</a></li>
<!-- wfParentRow start -->
<div class='NavType1Expander' id="nav10"><a href='#'>HTML5, XHTML, CSS & JavaScript</a></div>
<div class='NavType1Container' id="nav10Body">
<ul>
<!-- wfInner -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
<!-- wfInnerRowTpl -->
</ul>
</div>
<div class='NavType1ExpanderBase'></div>
<!-- wfParentRow end -->
<!-- wfCategoryFoldersTpl -->
<!-- wfInner -->
<!-- wfInnerRowTpl -->
<li><a href="index.php?id=12" title="Away3D 3.x" >Away3D 3.x</a></li>
<li><a href="index.php?id=23" title="Welcome" >Welcome</a></li>
<li class="last"><a href="http://google.co.uk" title="Test Web Link" >Test Web Link</a></li>
</div>
</div>
<!-- ########################### NAV END ########################### -->
The last 3 li's are:
<li><a href="index.php?id=12" title="Away3D 3.x" >Away3D 3.x</a></li>
Is setup as a category with no sub items (this will never happen).
<li><a href="index.php?id=23" title="Welcome" >Welcome</a></li>
Is setup as a page using the desired template, appears to be no way to style it via a snippet
<li class="last"><a href="http://google.co.uk" title="Test Web Link" >Test Web Link</a></li>
Is a resource link, but there is no way to style it using a snippet