Wow! I am by no means an extjs master, i can assure you.
That being said, i’ve worked with it several times and built many applications with it, and therefore has confortable with it has i am with jQuery.
Honestly, the best way to learn it is to load the example provided with the library and test, reproduce and ultimately, extend them.
Then, once you want to do anything, you have to refer to the API. There are less example than YUI but better API exposition (imo).
What’s difficult with MODExt is that all the components are wrapped within classes, and you need to know how to work with ext classes to use the components.
But it’s possible to also just load Extjs outside of MODx, and just run the example code provided with ExtJS in modx manager.
I’ll try to find some nice tutorial tomorrow, but i can’t garanty them to be geared toward beginners in javascript.
Note that i have learn many things directly from Sencha website:
http://www.sencha.com/learn/Tutorial:Ext_StartUp_Guide
And a couple of link that were useful to me:
http://www.marketplace3.extjs.com/learn/Tutorial:Extending_Ext_for_Newbies
http://www.sencha.com/forum/showthread.php?28085-Tutorial-Extending-an-Ext-Class
http://examples.extjs.eu/?ex=gridinacc