Get the id of the TV
Get the id of the template you will unbind the TV from
With the above look up all the documents that have the template ID above. See modx_site_content
Use the TV id with the list of document ids to delete rows from modx_site_tmplvar_contentvalues
For more info get familiar with the following tables
# modx_site_content
# modx_site_tmplvars
# modx_site_tmplvar_access
# modx_site_tmplvar_contentvalues
PS: I didn’t test this so make sure you make backups